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- Keira Knightley as Georgiana Cavendish
- Ralph Fiennes as William Cavendish
- Hayley Atwell as Lady Elizabeth 'Bess' Foster
- Charlotte Rampling as Georgiana Spencer
- Dominic Cooper as Charles Grey
- Aidan McArdle as Richard Brinsley Sheridan
- Simon McBurney as Charles James Fox
- Sebastian Applewhite as Augustus Clifford
- Calvin Dean as Devonshire House Servant
- Emily Jewell as Nanny
- Richard McCabe as Sir James Hare
- Alistair Petrie as Heaton
- Camilla Arfwedson as Lady Charlotte