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- Lindsay Lohan as Elizabeth Taylor
- Grant Bowler as Richard Burton
- Theresa Russell as Sara Taylor
- David Hunt as Ifor Jenkins
- Bruce Nozick as Bernard
- Tanya Franks as Sybil Burton
- Andy Hirsch as Eddie Fisher
- Charles Shaughnessy as Anthony Asquith
- David Eigenberg as Ernest Lehman
- Creed Bratton as Darryl Zanuck
- Taylor Ann Thompson as Kate Burton (age 10)
- Brian Howe as Joseph Mankiewicz
- Michael Matucci as Gianni Bulgari